N−H Imine as a Powerful Directing Group for Cobalt‐Catalyzed Olefin Hydroarylation

Habitat Simulation Technique as a Powerful Tool for Instream Flow Needs Assessment and River Ecosystem Management

Instream flow needs (IFN) assessment studies are performed to provide guidelines for stream water management and to assess the impacts of different water projects such as weirs, dams and stream diversions on the available fish habitat. The physical habitat simulation is one of the IFN assessment methods and also a powerful tool in management of river ecosystem that has not become a common metho...

Nanoparticles Poly Ethylene Imine-Functionalized MCM- as a Solid Catalyst for Multi-Component Reactions

A novel magnetically immobilized polyethyleneimine (PEI)fabricated by covalently anchoring on MCM-41 (MCM-41@PEI)was prepared. The synthesized catalyst was characterized by Fouriertransform infrared (FT-IR), thermogravimetric analysis (TGA), X-raypowder diffraction (XRD), scanning electron microscopy (SEM) andtransmission electron microscopy (TEM). The immobilized PEI wasshown to be an efficien...

Application of Genetic Programming as a Powerful Tool for Modeling of Cellulose Acetate Membrane Preparation

A traceless directing group for C-H borylation.

Not a trace: Borylation of the nitrogen in nitrogen heterocycles or anilines provides a traceless directing group for subsequent catalytic C-H borylation. Selectivities that previously required Boc protection can be achieved; furthermore, the NBpin directing group can be installed and removed in-situ, and product yields are substantially higher. Boc=tert-butoxycarbonyl, pin=pinacolato.

2,3-Dicyclohexylsuccinimide as a directing/protecting group for the regioselective glycosylation or alkylation of purines.

Here we describe the synthesis and application of a novel 2,3-dicyclohexylsuccinimide (Cy2SI) protecting group towards regioselective purine glycosylation and alkylation reactions. This bulky protecting group promotes high regioselectivity during the glycosylation (as well as diastereoselectivity) or alkylation of purines using Hoffer's chlorosugar or tert-butyl bromoacetate, respectively. Cy2S...